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A pyridine-thiol ligand with multiple bonding sites for heavy metal precipitation.

Author
Abstract
:

There are immediate concerns with current commercial ligands that are used for heavy metal precipitation, especially the limited arrays of bonding sites. Previous research has indicated that not only do commercial reagents lack sufficient bonding criteria, but they also fail to provide long-term stability as ligand-metal complexes. For this reason, we have developed a pyridine-based thiol ligand (DTPY) which not only offers multiple bonding sites for heavy metals but also should form stable metal-ligand precipitates. In this study, we used the divalent metals cadmium and copper to model the reactivity and pH stability of divalent metal complexes with the DTPY ligand. Using inductively-coupled plasma spectrometry (ICP), results indicate that a 50.00ppm (parts per million) copper solution, pH of 4.5, can be reduced to below the ICP detection limits of 0.00093ppm (>99.99% removal), and a 50.00ppm cadmium solution, pH of 6.0, can be reduced to 0.06ppm (99.88%).

Year of Publication
:
2001
Journal
:
Journal of hazardous materials
Volume
:
82
Issue
:
1
Number of Pages
:
55-63
Date Published
:
2001
ISSN Number
:
0304-3894
URL
:
https://linkinghub.elsevier.com/retrieve/pii/S0304-3894(00)00353-8
DOI
:
10.1016/s0304-3894(00)00353-8
Short Title
:
J Hazard Mater
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